Rutherford's Atomic Model
Rutherford's Atomic Model
This lesson aligns with NGSS PS1.A
Introduction
In the early 20th century, many scientists were on the edge of a revolutionary discovery that would reshape our understanding of the atom. The atomic model at that time, known as the "plum pudding" model, proposed by J.J. Thomson suggested atoms as a positively charged "pudding" with negatively charged electrons embedded within it like "plums." However, this model failed to explain certain experimental results associated with the atomic structure of elements. Therefore, an alpha particle scattering experiment was conducted, which ultimately led to Ernest Rutherford's nuclear model of the atom. In this article, we will learn about the Alpha particle scattering experiment and Rutherford’s nuclear model.
The Alpha Particle Scattering Experiment
Ernest Rutherford, along with his colleagues Hans Geiger and Ernest Marsden, conducted the alpha particle scattering experiment in 1909.
The experiment involved directing alpha particles, which are positively charged particles emitted by certain radioactive materials, at a thin (100 nm thickness) gold foil. The ZnS screen was placed behind the gold foil to detect the scintillations. The researchers expected the alpha particles to pass through the gold foil with minimal deflection, as predicted by the prevailing plum pudding model.
To their astonishment, the results of the experiment were far from what they anticipated. Most of the alpha particles did pass through the gold foil with little to no deviation. A small fraction approximately 1/1000th exhibited significant deflections because of a very strong positive charge in the centre of the atom. Some even bounced back because of the repulsion of its positive charge with some other positive charge inside the atom.
This unexpected outcome contradicted the predictions of the plum pudding model and hinted at the existence of a concentrated, positively charged nucleus within the atom.
Quantitative Insights from the Experiment
- A significant portion of the α-particles directed towards the gold foil passed through it without experiencing any deflection. Consequently, it was deduced that a considerable amount of space within an atom is vacant.
- Some α-particles exhibited minimal deflection when bombarded against the gold foil, indicating that the positive charge within an atom is not evenly spread out. Instead, the positive charge is concentrated within a remarkably small volume.
- Only a minority of α-particles were reflected back, with just a few achieving nearly a 180° angle of deflection. This observation implies that the volume occupied by positively charged particles within an atom is exceedingly minute when compared to the overall volume of the atom.
Rutherford's Nuclear Model
In light of the surprising findings from the alpha particle scattering experiment, Rutherford proposed a new model of the atom in 1911 – the nuclear model. Rutherford's model suggested that the positive charge within an atom is concentrated in a tiny, dense nucleus at its center. The electrons, which are negatively charged, orbit the nucleus at a distance.
The nucleus, according to Rutherford, is incredibly small compared to the overall size of the atom. The majority of the atom's volume is occupied by the empty space through which electrons move. This model successfully explained the results of the alpha particle scattering experiment, as the majority of alpha particles passed through the atom's empty space, while the deflections and rebounds occurred when alpha particles came close to the positively charged nucleus.
Limitations of Rutherford’s Atomic Model
- Rutherford's model suggested electrons orbit the nucleus in fixed paths, termed orbits. However, Maxwell's theory proposes that accelerated charged particles emit electromagnetic radiation. Consequently, an electron orbiting the nucleus, per Rutherford's model, should emit such radiation, leading to energy loss and the shrinking of orbits. Calculations indicate that, based on this model, electrons would collapse into the nucleus within less than 10-8 seconds, violating the stability observed in atoms. So Rutherford's model could not explain the stability of an atom.
- Rutherford didn’t explain the arrangement of electrons in an atom which made his theory incomplete.
Summary
- Rutherford along with his colleagues Hans Geiger and Ernest Marsden performed an alpha scattering experiment. They bombarded α-particles on a gold sheet and then studied the trajectory of these α-particles.
- The experiment revealed that the nucleus is much smaller than the size of the atom itself.
- Rutherford's model indicated that the nucleus occupies only a tiny fraction of the atom's volume, which was consistent with the experimental data.
Moreover, the model allowed scientists to estimate the charge of the nucleus, which turned out to be positively charged and responsible for the observed deflections of the alpha particles.
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